Go to the content. | Move to the navigation | Go to the site search | Go to the menu | Contacts | Accessibility

| Create Account

Burato, Claudio (2008) Un contributo all'utilizzo di idrogeno molecolare in processi ecocompatibili: sintesi diretta di H2O2. [Ph.D. thesis]

Full text disponibile come:

Documento PDF

Abstract (english)

Hydrogen peroxide, which annual world production is estimated in 3.5 mil tons/year, is prevalently used in paper industry, chemical synthesis and textile industry. The use of the green oxidant H2O2 is strongly recommended because of the high content of active oxygen and the formation of water as the only oxidation by-product. However, H2O2 is rather expensive, and today its wide employment is unfortunately far. The reaction of direct synthesis of hydrogen peroxide is know from 1914 and it can be considered as a possible strategic solution to obtain in an economic way diluite hydrogen peroxide solution. The Research Group where I carry out this Thesis work has a long experience in the activation of molecular hydrogen and oxygen upon using size controlled metal nanoclusters supported on cross-linked functional polymers. These type of catalysts, were synthesized, characterized by TEM, EXAFS, a-XRD and tested in the direct synthesis of hydrogen peroxide. With Pd°/K2621 catalysts, yields greater than 50% (respect the limiting reagent H2) after 90 minutes were obtained. A very promising catalyst was obtain upon generation of Pd° nanoclusters inside Nafion Sac-13. The support is a super acidic commercial material, obtained by dispersion of the perfluorinated polymer Nafion (13% w/w) on silica. This catalyst showed in the direct synthesis of hydrogen peroxide a very high selectivity (higher than 90%), respect to the limiting reagent H2.

Statistiche Download - Aggiungi a RefWorks
EPrint type:Ph.D. thesis
Tutor:Corain, Benedetto
Ph.D. course:Ciclo 20 > Scuole per il 20simo ciclo > SCIENZE MOLECOLARI > SCIENZE CHIMICHE
Data di deposito della tesi:2008
Anno di Pubblicazione:2008
Key Words:direct synthesis of hydrogen peroxide, metal nanoclusters, cross-linked fuctional polymers
Settori scientifico-disciplinari MIUR:Area 03 - Scienze chimiche > CHIM/04 Chimica industriale
Struttura di riferimento:Dipartimenti > Dipartimento di Scienze Chimiche
Codice ID:373
Depositato il:10 Sep 2008
Simple Metadata
Full Metadata
EndNote Format


I riferimenti della bibliografia possono essere cercati con Cerca la citazione di AIRE, copiando il titolo dell'articolo (o del libro) e la rivista (se presente) nei campi appositi di "Cerca la Citazione di AIRE".
Le url contenute in alcuni riferimenti sono raggiungibili cliccando sul link alla fine della citazione (Vai!) e tramite Google (Ricerca con Google). Il risultato dipende dalla formattazione della citazione.

[1] L. J. Thenard, Ann. Chim. Phys. 8 (1818) 306. Cerca con Google

[2] P. V. Rutledge, D. S. Bell (Laporte Chemicals Ltd.),GB 893 069, (1959). Cerca con Google

[3] Columbia-Southern Chemical Corp., US 2 904 517, 1959 (P. H. Baker). Cerca con Google

[4] Chem Week 167 (2005), 27. Cerca con Google

[5] K. Kosaka, H. Yamada, K shishida, S. Echigo, R.A. Minear, H. Tsuno, S. Matsui, Water Res. 35 (2001) 3587. Cerca con Google

[6] K. Sato, M. Aoki, J. Takagi and R. Noyori, J. Am. Chem. Soc., 119 (1997) 12386. Cerca con Google

[7] T Mashmeyer, F. Rey, G. Sankar, J. M. Thomas, Nature 378 (1995) 159. Cerca con Google

[8] R. van Grieken, J. L. Sotelo, C. Martos, J.L. Fierro, M. Lopez Granados, R. Mariscal, Catal Today 61 (2000) 855. Cerca con Google

[9] K. Sato, M. Hyodo, J. Takagi, M. Aoki and R. Noyori, Tetrahedron., 41 (2000) 1439. Cerca con Google

[10] K. Sato, M. Aoki, M. Ogawa, T. Hashimoto and R. Noyori, J. Org. Chem., 61 (1996) 8310. Cerca con Google

[11] S. Niwa M. Eswaramoorthy, J. Nair, F. Mizukami Science 295 (2002) 105. Cerca con Google

[12] C.D. Immanuel, F.J. Dole III, C.F. Cordeiro, S.S. Sundaram, AIChE J. 49 (2003) 1392. Cerca con Google

[13] B. Liu, M. Qiao, J. Wang, K. Fan, Chem. Commun. (2002) 1236. Cerca con Google

[14] X. Chen, H. Hu, B. Liu, M. Qiao, K. Fan, H. He, J. Catal. 220 (2003) 254. Cerca con Google

[15] R.A. Sheldon, J.K. Kochi in Metal-Catalyzed Oxidations of Organic Compounds, Academic Press, New York 1981. Cerca con Google

[16] H. Henkel, W. Weber, US Patent No 1,108,752 (1914). Cerca con Google

[17] P.N. Dyer, F. Moseley, (Air Products & Chemicals Inc) DE2710279 8 (1977). Cerca con Google

[18] L.W. Gosser (E.I: Du Pont de Nemours and Company) EP 132294 (1985). Cerca con Google

[19] C. Pralus, J.-P. Schirmann (Atochem ELF SA) EP 364374 (1990). Cerca con Google

[20] H. Nagashima, M. Ishiuchi, Y. Hiramatsu (Mitshubishi Gas Chemical Co) EP 504741 (1992). Cerca con Google

[21] S.P. Webb, J.A. McIntyre (Dow Chemical Co.) US 5800796 (1998). Cerca con Google

[22] M. Devic, L. Delais (Atofina) WO 9941190 (1999). Cerca con Google

[23] L. Kim, G.W. Shoenthal (Shell Oil) US 4,007,256 (1977). Cerca con Google

[24] G. Paparatto, R. D'Aloisio, G. De Alberti, R. Buzzoni (Eni) EP 1,160,196A1 (2001). Cerca con Google

[25] B. Betrsch-Frank, I. Hemme, L. Von Hoppel, S. Katusic, J. Rollmann, (Degussa Huls) US 6,387,346B1 (2002). Cerca con Google

[26] R. Burch, P.R. Ellis, Applied Catalysis B: Enviromental 42 (2003) 203. Cerca con Google

[27] G.B. Brieva, E. Cano-Serrano, J.M. Campos-Martin, J.L.G. Fierro Chem. Commun. (2004) 1184. Cerca con Google

[28] P. Landon, P.J. Collier, A. Carley, D. Chadwick, A.J. Papworth, A. Burrow, C. Kiely, G.J. Hutchings Phys. Chem. Chem. Phys. 5 (2003) 1917. Cerca con Google

[29] Hydrocarbon Process. 85 (2006) 29. Cerca con Google

[30] P. Mastrorilli, C. F. Nobile, N. Ravasio, B. Corain, M. Zecca J mol Catal 80 (1993) L5. Cerca con Google

[31] D. C. Sherrington, P. Hodge (ed.s) Synthesis and Separations using Functional Polymer Wiley, New York. Cerca con Google

[32] Macromolecular Division-IUPAC Raccomendetion2004. Cerca con Google

[33] W. O. Haag, D. D. Whitehurst (Mobil Oil) EP 1800371 (1969). Cerca con Google

[34] W. O. Haag, D. D. Whitehurst (Mobil Oil) EP 1800379 (1969). Cerca con Google

[35] R. H. Grubbs Chemtech 7 (1977) 512. Cerca con Google

[36] B. Corain, P. Centomo, M. Zecca Chim. Ind. 114 (2004) 86. Cerca con Google

[37] N. Yoneda, S. Kusano, M. Yasui, P. Pujado, S. Wilcher Appl. Catal. A: General 221 (2001) 253. Cerca con Google

[38] J. Wöllner, W. Neier EP 1260454 (1969). Cerca con Google

[39] B. Corain, P. Centomo, S. Lora, M. Kralik J. Mol. Cat. A. Chem 204-205 (2003) 755. Cerca con Google

[40] N.-H. Li, J. M. J. Frechet J. Chem. Soc. Chem. Commun (1985) 1100. Cerca con Google

[41] B. Corain, K. Jerá¡bek, P. Centomo, P. Canton Angew. Chem. In. Ed. 43 (2004) 959. Cerca con Google

[42] C. Burato, P. Centomo, G. Pace, M. Favaro, L. Prati, B. Corain J. Mol. Catal. A: Chemical 238 (2005) 26. Cerca con Google

[43] S. N. Sidorov, I. V. Volkov, V. A. Davankov J. Am. Chem. Soc. 123 (2001) 10502. Cerca con Google

[44] C. Ramarao, S. V. Ley, S. C. Smith, I. M. Shirley, N. DeAlmeida Chem. Commun. 1132 (2002). Cerca con Google

[45] S. V. Ley, C. Mitchell, D. Pears, C. Ramarao, J.-Q. Yu, W. Zhou Org. Lett. 4665 (2003). Cerca con Google

[46] Y. Uozumi, R. Nakao Angew. Chem. Int. Ed. 42 (2003) 194. Cerca con Google

[47] F. Shi, Y. Deng J. Catal. 211 (2002) 548. Cerca con Google

[48] R. Pool Science 248 (1990) 99. Cerca con Google

[49] S. C. Tjong. H. Chen Mat. Sci. Eng. R 45 (2004) 1. Cerca con Google

[50] G. Schmid Nanoparticles Wiley-VCH (2004). Cerca con Google

[51] G. Schmid Chem. Rev. 92 (1992) 1709. Cerca con Google

[52] M. Che, C. O. Bennet Adv. Catal. 36 (1989) 555. Cerca con Google

[53] M. Haruta, T. Kobayashi, H. Sano, N. Yamada Chem. Lett. 4 (1987) 405. Cerca con Google

[54] C. Milone, R. Ingoglia, A. Pistone, G. Neri, F. Frusteri, S. Galvagno J. Catal. 222 (2004) 348. Cerca con Google

[55] B. Coq N. Russo, D. R. Salahub Metal-Ligand Interactions Kluwer Academic Publishers, Dordrecht Cerca con Google

[56] G. J. Hutchings, Catal. Lett., 75 (2001) 1. Cerca con Google

[57] R. Wagner, P. M. Lange, Erdol Kohle Erdgas, 105 (1989) 414. Cerca con Google

[58] P. M. Lange, F. Martinola, S. Oeckel, Hydrocarbon Process, (1985) 51. Cerca con Google

[59] A. Biffis, R. Ricoveri, S. Campestrini, M. Kralik, K. Jerábek, Chem. Eur. J., 8 (2002) 2962. Cerca con Google

[60] A. Guyot, Synthesis and Separations using Functional Polymer, (D. C. Sherrington, P. Hodge (ed.s)), Wiley, New York, 1988. Cerca con Google

[61] R. Arshady, Adv. Mater., 3 (1991) 182. Cerca con Google

[62] A. Biffis, B. Corain, M. Zecca, C. Corvaja, K. Jerá¡bek, J. Am. Chem. Soc., 117 (1995) 1603. Cerca con Google

[63] A. A. D'Archivio, L. Galantini, A. Panatta, E. Tettamanti, B. Corain, J. Phys. Chem. B, 102 (1998) 6779. Cerca con Google

[64] B. Corain, M. Kralik, J. Mol. Catal. A: Chemical, 173 (2001) 99. Cerca con Google

[65] P. Centomo, M. Zecca, S. Lora, G. Vitulli, A. M. Caporusso, M. L. Tropeano, C. Milone, S. Galvagno, B. Corain, J. Catal., 229 (2005) 283. Cerca con Google

[66] F. M. Uhl, G. F. Leverik, C. Dick, J. J. Liggat, C. N. Snape, C. A. Wilkie, Polim. Degrad. Stabil., 71 (2001) 317. Cerca con Google

[67] G. Ertl, H. Knötzinger, J. Weitkamp, Handbook of Heterogeneous Catalysis, Jossey Bass: New York, 1997. Cerca con Google

[68] E. Gallei, E. Schwab, Catal. Today, 51 (1999) 535. Cerca con Google

[69] P. Claus, Appl. Catal. A: General, 291 (2005) 222. Cerca con Google

[70] M. Haruta, Chem. Rec., 3 (2003) 75. Cerca con Google

[71] A. Wolf, F. Schueth, Appl. Catal A: General, 226 (2001) 1. Cerca con Google

[72] S. Biella, L. Prati, M. Rossi, J. Catal., 206 (2002) 242. Cerca con Google

[73] C. L. Bianchi, S. Biella, A. Gervasini, L. Prati, M. Rossi, Catal. Lett., 85 (2003) 91. Cerca con Google

[74] L. Guczi, D. Horváith, Z. Pá¡szti, G. Petö, Catal. Today, 72 (1-2) (2002) 101. Cerca con Google

[75] F. Artuso, A. A. D'Archivio, S. Lora, K. Jerábek, M. Kralik, Chem. Eur. J., 9 (2003) 5292. Cerca con Google

[76] M. Kralik, V. Kratky, M. De Rosso, M. Tonelli, S. Lora, B. Corain, Chem. Eur. J., 9 (2003) 209. Cerca con Google

[77] B. Corain, C. Burato, P. Centomo, S. Lora, W. Meyer-Zaika, G. Schmid, J. Mol. Catal. A: Chemical, 225 (2004) 189. Cerca con Google

[78] M. Zecca, A. Biffis, G. Palma, C. Corvaja, S. Lora, K. Jerá¡bek, B. Corain, Macromolecules, 29 (1996) 4655. Cerca con Google

[79] B. Corain, M. Kralik, J. Mol. Catal. A: Chemical, 159 (2000) 153. Cerca con Google

[80] B. Corain, M. Zecca, K. Jerá¡bek, J. Mol. Catal. A: Chemical, 177 (2001) 3. Cerca con Google

[81] F. Pozzar, A. Sassi, G. Pace, S. Lora, A. A. D'Archivio, K. Jerá¡bek, A. Gra, Chem. Eur. J., 00 (2005) 00. Cerca con Google

[82] P. Hodge, Chem. Soc. Rev., 1 (1997) 417. Cerca con Google

[83] C. E. Harland, Ion exchange: Theory and Practice, Royal Society of Chemistry, 1994. Cerca con Google

[84] K. Jerabek, Anal. Chem.,57 (1985) 1598. Cerca con Google

[85] K. Jerabek in Cross Evaluation of Strategics in Size-Exclusion Chromathography, ACS Symposium Series 635 (M. Potschka, P.L.Bubbin Ed.s) 211 (1996). Cerca con Google

[86] G. Ogston, Trans. Faraday Soc., 54 (1958) 1754. Cerca con Google

[87] D. P. Dissanayake, J. H. Lunsford J. Catal 214 (2003) 113. Cerca con Google

[88] V. R. Choudhary, A. G. Gaikwad, S. D. Sansare Angew. Chem 40 (2001) 1776. Cerca con Google

[89] S. Abate, G. Centi, S. Melada, S. Perathoner, F. Pinna, G. Strukul, Catal Today 104 (2005) 123. Cerca con Google

[90] Q. Chen, E. J. Beckman Green Chem. 9 (2007) 802. Cerca con Google

[91] V. R. Choudhary, C. Samanta, T. V. Choudhary Appl. Catal. A. 308 (2006) 128. Cerca con Google

[92] T. Ishihara, Y. Ohura, s. Yoshida, Y. Hata, Y. Takita Appl. Catal. A 291 (2005) 215. Cerca con Google

[93] H.B. Liu, U. Pal, A. Medina, C. Maldonado, A. Ascensio Phis Rew. B. 71 (2005) 75403. Cerca con Google

[94] J. A. Ascencio, H. B. Liu, U. Pal, A. Medina, and Z. L. Wang, Microsc. Res. Tech. to be published. Cerca con Google

[95] J. K Edwards, A. Thomas, B. Solsona, P. Landon, A. Carley, G. Hatchings Catal Today 000 (2007) 000. Cerca con Google

[96] C. Samanta, V. R. Choudhary, Catal. Commun. 8 (2007) 73. Cerca con Google

[97] V. R. Choudhary, C. Samanta, G. Gaikwad, Chem. Commun. 2054 (2004). Cerca con Google

[98] V.V. Krishnan, A.G. Dokoutchaev, M. E. Thompson, J. Catal. 196 (2000) 366. Cerca con Google

[99] D. Hancu, E. Beckman Green Chem 2001 3 80. Cerca con Google

[100] Mitsubishi Gas Chemical Company, Inc. EP 0 623 552 B1 Cerca con Google

[101] S. K. Ihm, M. J. Chung, K.Y. Park Ind. Eng. Chem. Res.1, 27 (1988) 42 Cerca con Google

[102] C. Burato, P. Centomo, M. Rizzoli, A. Biffis, S. Campestrini, B. Corain, Adv. Synth. Catal. 348 (2006) 255. Cerca con Google

[103] Y.F. Han, J. H. Lunsford Catal Lett.99 (2005) 13. Cerca con Google

[104] A.I. Dalton, R.W. Skinner, EP 49806 (1982) Cerca con Google

[105] J. Herney Ramirez, C. A. Costa, L.M. Madeira Catalysis Today 107 (2005) 68 Cerca con Google

[106] T. Teranishi, M. Miyake Chem. Mater. 10, (1998), 594 Cerca con Google

[107] V.R. Choudhary, C. Samanta, P. Jana, Appl. Catal A. 317 (2007) 234. Cerca con Google

[108] Y.F.Han, J.H. Lunsford, J. Catal. 230 (2005) 313. Cerca con Google

[109] M. A. Harmer, W. E. Farneth, Q. Sun, J. am. Chem. Soc. 118 (1996) 7708 Cerca con Google

[110] N. Blake, M. Peterson, G. Voth, H. Metiu J. Phys. Chem. B 109 (2005) 24244 Cerca con Google

Download statistics

Solo per lo Staff dell Archivio: Modifica questo record