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Ponsot, Inès (2015) Glasses and Glass-Ceramic Components from Inorganic Waste and Novel Processing. [Tesi di dottorato]

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Abstract (inglese)

Thanks to European environmental rules and regulations establishment, waste recycling has become a more and more relevant problematic. For manufacturing plants, especially those producing hazardous wastes, expenses linked to waste production have drastically increased over the last decades. In the proposed work, various hazardous and non-hazardous wastes, among: soda-lime and borosilicate glass cullet, cathode ray tubes glass, exhausted lime from fume abatement systems residues, sludge and slags from ferrous and non-ferrous metallurgy, and pre-stabilized municipal solid waste incinerators ashes are used to elaborate several compositions of glass-ceramics. High-temperature treatment (minimum 800 °C) associated to a Direct Sintering process (30 min) was an efficient way to stabilize chemically the final products. The impact of each waste on the final product’s mechanical properties was studied, but also their synergies between each other, when mixed together. Statistic mixture designs enabled to develop interesting products for modern building applications, such as porous tiles and lightweight panels destined to insulation, with a purpose of fulfilling multifunctional properties.

Abstract (italiano)

Grazie alle regole e normative ambientali europee istituite, il riciclaggio dei rifiuti è diventato una problematica sempre più rilevante. Per gli impianti di produzione, in particolare quelli che producono rifiuti pericolosi, le spese connesse allo smaltimento sono drasticamente aumentate negli ultimi decenni. Nel lavoro proposto, vari rifiuti, pericolosi o no, vengono utilizzati per elaborare diverse composizioni di vetroceramiche. Si distinguono rottami di vetro della produzione di finestre, di contenitori farmaceutici e di tubi catodici. I rifiuti non vetrosi invece sono calce esausta da residui di sistemi di filtrazione di fumi, scorie metallurgiche da leghe ferrose e non e ceneri da inceneritori. E' presentata nel presente lavoro la ricerca di un metodo di trattamento ad alta temperatura (minima 800 ° C) efficace per stabilizzare chimicamente il prodotto finale, tramite i diversi processi di sinterizzazione diretta, sinter-cristallizzazione e vetrificazione. Sono stati studiati gli effetti di ogni rifiuto sulle proprietà meccaniche del prodotto finale, ma anche le nuove funzionalità ottenute attraverso le sinergie risultanti dalla loro miscela. Miscele calibrate hanno permesso di sviluppare prodotti interessanti per applicazioni edilizie moderne, come le piastrelle porose e pannelli leggeri destinati all’isolamento.

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Tipo di EPrint:Tesi di dottorato
Relatore:Bernardo, Enrico
Dottorato (corsi e scuole):Ciclo 27 > scuole 27 > INGEGNERIA INDUSTRIALE > INGEGNERIA CHIMICA, DEI MATERIALI E DELLA PRODUZIONE
Data di deposito della tesi:28 Gennaio 2015
Anno di Pubblicazione:28 Gennaio 2015
Parole chiave (italiano / inglese):Sintering; viscous flow sintering; X-ray methods; Mechanical properties: magnetic glass ceramics; induction heating; iron-rich slags; borosilicate glass; cytotoxicity tests; Glass-ceramic, waste, viscous flow sintering, sinter-crystallization; Fast sintering, X Ray Diffraction, Chemical tempering methods, Glass ceramics, Nepheline,; Ion exchange, CRT Glass,; Bending strength, Porous ceramics.; Glass-ceramic, metallurgical waste, viscous flow sintering, crystallization; Glass-ceramic, waste, viscous flow sintering, sinter-crystallization; MSWI fly ash; fayalite; wollastonite; Glass ceramics; Cytotoxicity; Glass ceramics; X-ray diffraction; Industrial waste; Iron slag; Sintering; Mechanical properties, Glass ceramics, Structural applications, Oil shale ash, Sinter crystallisation; blast furnace sludge; leaching procedure; glass cullet; inorganic waste; industrial wastes; recycled glass; soda-lime glass; borosilicate glass; exhausted lime; cathod ray tube glass: crt glass; vicker hardness; SiC; silicon carbide; preceramic polymers; glass; foamed glass; novel processing; direct sintering; electromagnetic shielding effectiveness; induction heating; TCLP; EN 12457; industrial ceramics; recycling; valorization Sinterrizzatione; sinterizazzione in flusso viscoso; metodo raggi x; proprietà mecchaniche; vetroceramiche; vetro-ceramiche; vetroceramiche magnetiche; vetroceramica magnetica; rifiuti ricci di ferro; rifiuti industriale; rifiuti industriali; rifiuti inorganici; vetri di scarto; vetro da tubi cathodici; applicazioni strutturali; citossicità; lisciviazione; eluato; materiali porosi; materiali da recupero: materiali cellulari; materiali compositi; SiC; tenacità vickers; polimeri preceramici; carburo di silicio; scorie metallurgiche; scoria di metallurgia ferrosa; wollastonite; anortite; nefeline; calce esausta; sinterizzazione diretta; efficienza di schermatura elettromagnetica; riscaldamento per induzione; TCLP; EN 12457; prova di lisciviazione; ceramiche industriale; riclico; valorizzazione
Settori scientifico-disciplinari MIUR:Area 09 - Ingegneria industriale e dell'informazione > ING-IND/22 Scienza e tecnologia dei materiali
Struttura di riferimento:Dipartimenti > Dipartimento di Ingegneria Industriale
Codice ID:7672
Depositato il:23 Nov 2015 14:25
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