The present research has the goal to equip an electrochemical microscopy laboratory able to study charge transfer (CT) reactions across interfaces of different kind. This goal has been reached acquiring the knowhow of the micro tips fabrication and setting up experimental systems for CT measurements at different type of interfaces. The Scanning ElectroChemical Microscopy (SECM) is used widely and the project involved the study of three kind of interfaces: a liquid/liquid ITIES, that is an Interface between Two Immiscible Electrolyte Solutions, a liquid/solid interface, formed by a glassy substrate covered by a thin film of silica with a Ruthenium(II) tris-bipyridile complex chemically linked to the lattice; and the last one was a liquid/swollen polymer interface.

Studi di trasferimento di carica ad interfacce / Instuli, Emanuele. - (2008 Jan).

Studi di trasferimento di carica ad interfacce

Instuli, Emanuele
2008

Abstract

The present research has the goal to equip an electrochemical microscopy laboratory able to study charge transfer (CT) reactions across interfaces of different kind. This goal has been reached acquiring the knowhow of the micro tips fabrication and setting up experimental systems for CT measurements at different type of interfaces. The Scanning ElectroChemical Microscopy (SECM) is used widely and the project involved the study of three kind of interfaces: a liquid/liquid ITIES, that is an Interface between Two Immiscible Electrolyte Solutions, a liquid/solid interface, formed by a glassy substrate covered by a thin film of silica with a Ruthenium(II) tris-bipyridile complex chemically linked to the lattice; and the last one was a liquid/swollen polymer interface.
gen-2008
electrochemistry; Scanning Electrochemical Microscopy; liquid interface; microtips
Studi di trasferimento di carica ad interfacce / Instuli, Emanuele. - (2008 Jan).
File in questo prodotto:
File Dimensione Formato  
Tesi_Emanuele_Instuli_Phd.pdf

accesso aperto

Tipologia: Tesi di dottorato
Licenza: Non specificato
Dimensione 3.93 MB
Formato Adobe PDF
3.93 MB Adobe PDF Visualizza/Apri
Pubblicazioni consigliate

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11577/3425489
Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus ND
  • ???jsp.display-item.citation.isi??? ND
social impact