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Guryanov, Ivan (2008) 310-Helical peptides as spacers and templates for spectroscopic studies and organic syntheses. [Ph.D. thesis]

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Abstract (english)

In this Ph.D. thesis rigid peptide 310-helical structures were applied for the design of rigid templates and spacers for different spectroscopic and photophysical studies as well as for organic syntheses. In particular, the influence of the macroscopic dipole of the peptide 310-helix on the electron transfer between the azulene and pyrene chromophoric moieties was investigated. Such structures were used also in FT-IR spectroscopy and exciton coupled CD method for the study of peculiarities of these tecnics. Finally, 310-helical peptides were served as templates for organic synthesis to enhance the helical stability of peptides.


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EPrint type:Ph.D. thesis
Tutor:Formaggio, Fernando
Ph.D. course:Ciclo 20 > Scuole per il 20simo ciclo > SCIENZE MOLECOLARI > SCIENZE CHIMICHE
Data di deposito della tesi:31 January 2008
Anno di Pubblicazione:31 January 2008
Key Words:310-helix, porphyrin, ring-closing metathesis, isotope-edited FT-IR
Settori scientifico-disciplinari MIUR:Area 03 - Scienze chimiche > CHIM/06 Chimica organica
Struttura di riferimento:Dipartimenti > Dipartimento di Scienze Chimiche
Codice ID:972
Depositato il:24 Nov 2008
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